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ACTIVITY 1

LABORATORY PREPARATION OF ALKANES

School laboratory preparation of alkanes

In a school laboratory, alkanes may be prepared from the reaction of a sodium alkanoate with solid sodium hydroxide /soda lime.

Chemical equation:

Sodium alkanoate+soda lime -> alkane +Sodium carbonate

C2 H2n+2 COONa(s)   +NaOH(s)  ->  C2 H2n+2 + Na2CO3(s)

The “H” in NaOH is transferred/moves to the CnH2n+1 in CnH2n+1COONa(s) to form C2 H2n+2.

Examples

  1. Methane is prepared from the heating of a mixture of sodium ethanoate and soda lime and collecting over water
  2. Sodium ethanoate  +  soda lime->

           methane + Sodium carbonate

    CH3COONa(s) +NaOH(s) ->C H4  +  Na2CO3(s)

    The “H” in NaOH is transferred/moves to the CH3 in CH3COONa(s) to form CH4.

    1. Ethane is prepared from the heating of a mixture of sodium propanoate and soda lime and collecting over water

    Sodium propanoate +  soda lime->

      ethane+Sodium carbonate

    CH3 CH2COONa(s) +NaOH(s)->CH3 CH3 +Na2CO3(s)

    The “H” in NaOH is transferred/moves to the CH3 CH2 in CH3 CH2COONa (s) to form CH3 CH3

write the balanced chemical equation for the above reaction